Group Holiday Party 2011
photos/group2011.jpg(back)Lana, Ted, Art, Raul, Graham, Dave, Emily
(front) Doug, Benji, Alison, Libby, Tamara, Austin, Evan and Matt
(not pictured: Denise, Annie, and Richard)
C−H Bond Amination from a Ferrous Dipyrromethene Complex
photos/one.jpgKing, E.R.; Betley, T.A. Inorg. Chem., 2009, 48(6), 2361.
Unusual Electronic Structure of First Row Transition Metal Complexes Featuring Redox-Active Dipyrromethane Ligands
photos/two.jpgKing, E.R.; Betley, T.A. JACS, 2009, 131(40), 14374.
ACS Meeting Spring 2012
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Ligand-Centered Redox Activity: Redox Properties of 3d Transition Metal Ions Ligated by the Weak-Field Tris(pyrrolyl)ethane Trianion
photos/three.jpgSazama, G.T.; Betley, T.A. Inorg. Chem., 2010, 49(5), 2512.
Synthesis and Redox Properties of Triiron Complexes Featuring Strong Fe–Fe Interactions
photos/four.jpgDr. Qinliang Zhao, Prof. Theodore A. BetleyACIE, 2011, 50(3), 709.
ACS Meeting Spring 2012
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Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ3-Nitride, [Fe3(μ3-N)]−
photos/five.jpgPowers, T.M.; Four, A.R.; Zheng, S.L.; Betley, T.A.JACS, 2011, 133(10), 3336.
Catalytic C-H Bond Amination from High-Spin Iron Imido Complexes
photos/six.jpgKing, E.R.; Hennessy, E.T.; Betley, T.A.JACS, 2011, 133(13), 4917.
[(HL)2Fe6(NCMe)m]n+ (m = 0, 2, 4, 6; n = −1, 0, 1, 2, 3, 4, 6): An Electron-Transfer Series Featuring Octahedral Fe6 Clusters Supported by a Hexaamide Ligand Platform
photos/seven.jpgZhao, Q.; Harris, T.D.; Betley, T.A. JACS, 2011, 133(21), 8293.
Group Holiday Party 2011
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Expanded redox accessibility via ligand substitution in an octahedral Fe6Br6 cluster
photos/eight.jpgHarris, T.D.; Hernandez Sanchez, R.; Betley, T.A. Chem. Commun., 2011, 47, 6344.
Electronic Perturbations of Iron Dipyrrinato Complexes via Ligand β-Halogenation and meso-Fluoroarylation
photos/nine.jpgScharf, A.B.; Betley, T.A. Inorg. Chem., 2011, 50(14), 6837.
Reductive Coupling of CO Templated by Iron Bound to the Tris(pyrrolide)ethane Scaffold
photos/ten.jpgSazama, G.T.; Betley, T.A. Organometallics, 2011, 30(16), 4315.
Multi-Site Reactivity: Reduction of Six Equivalents of Nitrite To Give an Fe6(NO)6 Cluster with a Dramatically Expanded Octahedral Core
photos/eleven.jpgHarris, T.D.; Betley, T.A. JACS, 2011, 133(35), 13852.
Oxidative Atom-Transfer to a Trimanganese Complex To Form Mn6(μ6-E) (E = O, N) Clusters Featuring Interstitial Oxide and Nitride Functionalities
photos/twelve.jpgFout, A.R.; Zhao, Q.; Xiao, D.J.; Betley, T.A. JACS, 2011, 133(42), 16750.
Modulation of magnetic behavior via ligand-field effects in the trigonal clusters (PhL)Fe3L*3 (L* = thf, py, PMe2Ph)
photos/thirteen.jpgEames, E.V.; Harris, T.D.; Betley, T.A. Chem. Sci., 2012, 3, 407.
April 2012
Matt wins an NSF Graduate Fellowship, congratulations!
Libby is the 2012 Pfizer award for inorganic chemistry at Harvard! We can't wait to hear her award lecture!
March 2012
Congratulations to Alison and Dave for accepting professorships at University of Illinois and Northwestern
December 2011
Denise, Matt and Benji joined the group!
October 2011
Emily and Dave’s publication demonstrates the ability to modulate the magnetic behavior via ligand-field effects on triiron clusters!
September 2011
Alison, Kin and Dianne report on the JACS publication the μ6-oxido and -nitrido functionalities on an octahedral Mn6 cluster!
August 2011
Reactivity of the Fe6 octahedral core is demonstrated in the paper “Multi-Site Reactivity: Reduction of Six Equivalents of Nitrite To Give an Fe6(NO)6 Cluster with a Dramatically Expanded Octahedral Core” published by Dave in JACS!
July 2011
Graham’s second paper, on the “Reductive coupling of CO Templated by Iron Bound to the Tris(pyrrolide)ethane Scaffold is published in Organometallics!
June 2011
Austin’s paper on the “Electronic Perturbations of Iron Dipyrrinato Complexes via Ligand β-Halogenation and meso-Fluorination” is published in IC!