Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

Hennessy, E.T.; Betley, T.A. Science, 2013, 340, 591.

ACS National Meeting Spring 2013

The group relaxes in New Orleans during the Spring 2013 ACS National Meeting

Metal Atom Lability in Polynuclear Complexes

Eames, E.V.; Hernández Sánchez, R.; Betley, T.A. Inorg. Chem, 2013, ASAP

Co(III) Imidos Exhibiting Spin Crossover and C–H Bond Activation

King, E.R.; Sazama, G.T.; Betley, T.A. JACS, 2012 ASAP

ACS Meeting Spring 2012

Trigonal Mn₃ and Co₃ Clusters Supported by Weak-Field Ligands: A Structural, Spectroscopic, Magnetic, and Computational Investigation into the Correlation of Molecular and Electronic Structure

Fout, A.R.; Xiao, D.J.; Zhao, Q.; Harris, T.D.; King, E.R.; Eames, E.V.; Zheng, S.; Betley, T.A. Inorg. Chem., 2012, 19, 10290.

Group Summer Outing

Site-Isolated Redox Reactivity in a Trinuclear Iron Complex

Eames, E.V.; Betley, T.A. Inorg. Chem., 2012, 19, 10274.

Inorganic Supergroup 2012

Softball following a meeting of our group, the Byers Group(Boston College), the Dinca Group (MIT), and the Thomas Group(Brandeis) on July 27, 2012

Modulation of magnetic behavior via ligand-field effects in the trigonal clusters (^PhL)Fe₃L*₃ (L* = thf, py, PMe₂Ph)

Eames, E.V.; Harris, T.D.; Betley, T.A. Chem. Sci., 2012, 3, 407.

Group at Evan's Defense

(back) Dave, Graham, Emily
(front) Austin, Benji, Raul, Ted, Evan, Matt, Libby, Denise, and Tamara
(left to right)

ACS Meeting Spring 2012

Oxidative Atom-Transfer to a Trimanganese Complex To Form Mn₆(μ⁶-E) (E = O, N) Clusters Featuring Interstitial Oxide and Nitride Functionalities

Fout, A.R.; Zhao, Q.; Xiao, D.J.; Betley, T.A. JACS, 2011, 133(42), 16750.

Multi-Site Reactivity: Reduction of Six Equivalents of Nitrite To Give an Fe₆(NO)₆ Cluster with a Dramatically Expanded Octahedral Core

Harris, T.D.; Betley, T.A. JACS, 2011, 133(35), 13852.

Group Holiday Party 2011

Reductive Coupling of CO Templated by Iron Bound to the Tris(pyrrolide)ethane Scaffold

Sazama, G.T.; Betley, T.A. Organometallics, 2011, 30(16), 4315.

Electronic Perturbations of Iron Dipyrrinato Complexes via Ligand β-Halogenation and meso-Fluoroarylation

Scharf, A.B.; Betley, T.A. Inorg. Chem., 2011, 50(14), 6837.

Group Holiday Party 2011

(back)Lana, Ted, Art, Raul, Graham, Dave, Emily
(front) Doug, Benji, Alison, Libby, Tamara, Austin, Evan and Matt
(not pictured: Denise, Annie, and Richard)

Expanded redox accessibility via ligand substitution in an octahedral Fe₆Br₆ cluster

Harris, T.D.; Hernandez Sanchez, R.; Betley, T.A. Chem. Commun., 2011, 47, 6344.

[(^HL)₂Fe₆(NCMe)_m]ⁿ⁺ (m = 0, 2, 4, 6; n = −1, 0, 1, 2, 3, 4, 6): An Electron-Transfer Series Featuring Octahedral Fe₆ Clusters Supported by a Hexaamide Ligand Platform

Zhao, Q.; Harris, T.D.; Betley, T.A. JACS, 2011, 133(21), 8293.

Catalytic C-H Bond Amination from High-Spin Iron Imido Complexes

King, E.R.; Hennessy, E.T.; Betley, T.A. JACS, 2011, 133(13), 4917.

Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ³-Nitride, [Fe₃(μ³-N)]⁻

Powers, T.M.; Fout, A.R.; Zheng, S.L.; Betley, T.A. JACS, 2011, 133(10), 3336.

Synthesis and Redox Properties of Triiron Complexes Featuring Strong Fe–Fe Interactions

Dr. Qinliang Zhao, Betley, T.A. ACIE, 2011, 50(3), 709.

Ligand-Centered Redox Activity: Redox Properties of 3d Transition Metal Ions Ligated by the Weak-Field Tris(pyrrolyl)ethane Trianion

Sazama, G.T.; Betley, T.A. Inorg. Chem., 2010, 49(5), 2512.

C−H Bond Amination from a Ferrous Dipyrromethene Complex

King, E.R.; Betley, T.A. Inorg. Chem., 2009, 48(6), 2361.

Unusual Electronic Structure of First Row Transition Metal Complexes Featuring Redox-Active Dipyrromethane Ligands

King, E.R.; Betley, T.A. JACS, 2009, 131(40), 14374.